<?xml version="1.0" encoding="utf-8" ?>
<Biodata>
  <Name>GRENGANATHAN</Name>
  <age>20</age>
  <Qualification>Msc</Qualification>
</Biodata>

Imports System.Data

Partial Class _Default
    Inherits System.Web.UI.Page

    Protected Sub Page_Load(ByVal sender As Object, ByVal e As System.EventArgs) Handles Me.Load
        Dim ds As New dataset
        ds.ReadXml("file:///C:\DotNetProjects\ArrayListDropdownlist\XMLFile.xml")
        GridView1.DataSource = ds
        GridView1.DataBind()

    End Sub
End Class